Jiangsu Zijun International Trade Co., Ltd.

Jiangsu Zijun International Trade Co., Ltd.

POE vs POP: Core Differences & Selection Guide

2026 05/22

Synthesis & Structural Root

Both materials are synthesized via metallocene catalysis but differ in comonomer design:

POE (Polyolefin Elastomer): Copolymer of ethylene and 1-octene (comonomer content >= 20 mol%) with an amorphous structure. It behaves like rubber, providing excellent flexibility and impact resistance.

POP (Polyolefin Plastomer): Copolymer of ethylene and 1-butene/1-hexene (comonomer content < 20 mol%) with higher molecular chain regularity. It behaves like functional plastic, balancing toughness and rigidity.

POE vs POP

Core Physical Properties

Property Dimension POE (Polyolefin Elastomer) POP (Polyolefin Plastomer)
Density 0.855–0.880 g/cm3 (Ultra-low density) 0.880–0.915 g/cm3 (Medium-low density)
Hardness Shore A 70–90 (Soft rubber tactile feel) Shore D range (Harder plastic tactile feel)
Mechanicals High elasticity, low permanent set High rigidity, superior tensile strength
Low-Temp Toughness Extreme (No brittle failure at -40°C) Good, but inferior to POE
Optical Translucent, moderate haze Highly transparent, low haze, superior clarity
 

Industry Applications

POE (Focus on Toughness & Elasticity)

Plastic Modification: Acts as an impact modifier/toughening agent for PP/PE in automotive bumpers, interior parts, and home appliance casings.

New Energy: Core encapsulation film substrate for photovoltaic (PV) solar modules due to excellent UV and weathering resistance.

Wire & Cable: Insulation and jacketing layers that require excellent low-temperature flexibility and bending resistance.

POP (Focus on Sealing & Clarity)

Flexible Packaging: Used as the heat-seal layer for high-speed food and medical packaging films, offering low seal-initiation temperature (SIT) and anti-contamination sealing.

Hot-Melt Adhesives: Serves as the base polymer for premium polyolefin hot-melt adhesives in packaging and automotive assembly.

Rigidity-Retained Modification: Ideal for compounding scenarios where both impact blending toughness and component rigidity retention are required.

Quick Procurement Rule

Choose POE if your priority is: Low-temperature impact modification, elasticity enhancement, plastic compounding, or PV encapsulation weatherability.

Choose POP if your priority is: High-speed film production, low-temperature heat sealing, high transparency, tear resistance, or retaining product rigidity.